135,815 research outputs found

    Triaxial projected shell model approach

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    The projected shell model analysis is carried out using the triaxial Nilsson+BCS basis. It is demonstrated that, for an accurate description of the moments of inertia in the transitional region, it is necessary to take the triaxiality into account and perform the three-dimensional angular-momentum projection from the triaxial Nilsson+BCS intrinsic wavefunction.Comment: 9 pages, 2 figure

    Kinetics of dissociative chemisorption of methane and ethane on Pt(110)-(1X2)

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    The initial probability of dissociative chemisorption Pr of methane and ethane on the highly corrugated, reconstructed Pt(110)‐(1×2) surface has been measured in a microreactor by counting the number of carbon atoms on the surface following the reaction of methane and ethane on the surface which was held at various constant temperatures between 450 and 900 K during the reaction. Methane dissociatively chemisorbs on the Pt(110)‐(1×2) surface with an apparent activation energy of 14.4 kcal/mol and an apparent preexponential factor of 0.6. Ethane chemisorbs dissociatively with an apparent activation energy of 2.8 kcal/mol and an apparent preexponential factor of 4.7×10^(−3). Kinetic isotope effects were observed for both reactions. The fact that P_r is a strong function of surface temperature implies that the dissociation reactions proceed via a trapping‐mediated mechanism. A model based on a trapping‐mediated mechanism is used to explain the observed kinetic behavior. Kinetic parameters for C–H bond dissociation of the thermally accommodated methane and ethane are extracted from the model

    Microscopic Description of Band Structure at Very Extended Shapes in the A ~ 110 Mass Region

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    Recent experiments have confirmed the existence of rotational bands in the A \~ 110 mass region with very extended shapes lying between super- and hyper-deformation. Using the projected shell model, we make a first attempt to describe quantitatively such a band structure in 108Cd. Excellent agreement is achieved in the dynamic moment of inertia J(2) calculation. This allows us to suggest the spin values for the energy levels, which are experimentally unknown. It is found that at this large deformation, the sharply down-sloping orbitals in the proton i_{13/2} subshell are responsible for the irregularity in the experimental J(2), and the wave functions of the observed states have a dominant component of two-quasiparticles from these orbitals. Measurement of transition quadrupole moments and g-factors will test these findings, and thus can provide a deeper understanding of the band structure at very extended shapes.Comment: 4 pages, 3 eps figures, final version accepted by Phys. Rev. C as a Rapid Communicatio

    Space-Time Sampling for Network Observability

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    Designing sparse sampling strategies is one of the important components in having resilient estimation and control in networked systems as they make network design problems more cost-effective due to their reduced sampling requirements and less fragile to where and when samples are collected. It is shown that under what conditions taking coarse samples from a network will contain the same amount of information as a more finer set of samples. Our goal is to estimate initial condition of linear time-invariant networks using a set of noisy measurements. The observability condition is reformulated as the frame condition, where one can easily trace location and time stamps of each sample. We compare estimation quality of various sampling strategies using estimation measures, which depend on spectrum of the corresponding frame operators. Using properties of the minimal polynomial of the state matrix, deterministic and randomized methods are suggested to construct observability frames. Intrinsic tradeoffs assert that collecting samples from fewer subsystems dictates taking more samples (in average) per subsystem. Three scalable algorithms are developed to generate sparse space-time sampling strategies with explicit error bounds.Comment: Submitted to IEEE TAC (Revised Version
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